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91.
Chenxu Ding Lingyun Wang Chunliang Tian Yulin Li Zhiwei Sun Honglun Wang Yourui Suo Jinmao You 《Chromatographia》2008,68(11-12):893-902
A novel labeling reagent 1-(2-naphthyl)-3-methyl-5-pyrazolone (NMP) coupling to liquid chromatography with electrospray ionization mass spectrometry for the detection of carbohydrates from the derivatized rape bee pollen samples is reported. Carbohydrates are derivatized to their bis-NMP-labeled derivatives. Derivatives showed an intense protonated molecular ion at m/z [M+H]+ in positive-ion detection mode. The mass-to-charge ratios of characteristic fragment ions at m/z 473.0 could be used for the accurately qualitative analysis of carbohydrates. This characteristic fragment ion is from the cleavage of C2–C3 bond in carbohydrate chain giving the specific fragment ions at m/z [MH-C m H2m+1O m -H2O]+ for pentose, hexose and glyceraldehydes and at m/z [MH-C m H2m-1O m+1-H2O]+ for alduronic acids such as galacturonic acid and glucuronic acid (m = n ? 2, n is carbon number of carbohydrate). No interferences for all aliphatic and aromatic aldehydes presented in natural environmental samples were observed due to the highly specific parent mass-to-charge ratio and the characteristic fragment ions. The method, in conjunction with a gradient elution, offered a baseline resolution of carbohydrate derivatives on a reversed-phase Hypersil ODS-2 column. The carbohydrates such as mannose, galacturonic acid, glucuronic acid, rhamnose, glucose, galactose, xylose, arabinose and fucose can successfully be detected. 相似文献
92.
93.
利用深能级瞬态谱(DLTS)研究了气源分子束外延(GSMBE)生长的InP1-xBix材料中深能级中心的性质。在未有意掺杂的InP中测量到一个多数载流子深能级中心E1,E1的能级位置为Ec-0.38 e V,俘获截面为1.87×10~(-15)cm~2。在未有意掺杂的InP0.9751Bi0.0249中测量到一个少数载流子深能级中心H1,H1的能级位置为Ev+0.31 eV,俘获截面为2.87×10~(-17)cm~2。深中心E1应该起源于本征反位缺陷PIn,深中心H1可能来源于形成的Bi原子对或者更复杂的与Bi相关的团簇。明确这些缺陷的起源对于InPBi材料在器件应用方面具有重要的意义。 相似文献
94.
In this paper, by means of monotone iterative technique, a necessary and sufficient condition of the existence of positive solution for a class of nonlinear singular differential system is established, the results of the existence and uniqueness of the positive solution and the iterative sequence of solution are given. In the end, two classes extending boundary value differential systems are discussed and some further results are obtained. 相似文献
95.
The purpose of the present note is to establish some new delay integral inequalities, which provide explicit bounds on unknown functions and generalize some results of Li et al. [Some new delay integral inequalities and their applications, J. Comput. Appl. Math. 180 (2005) 191–200]. The inequalities given here can be used to investigate the qualitative properties of certain delay differential equations and delay integral equations. 相似文献
96.
By fixed point index theory and a result obtained by Amann, existence of the solution for a class of nonlinear operator equations x=Ax is discussed. Under suitable conditions, a couple of positive and negative solutions are obtained. Finally, the abstract result is applied to nonlinear Sturm-Liouville boundary value problem, and at least four distinct solutions are obtained. 相似文献
97.
《Nonlinear Analysis: Real World Applications》2007,8(4):1235-1251
We study the irrotational subsonic stationary solutions of a multi-dimensional nonisentropic hydrodynamic model for semiconductor devices. This model consists of the continuous equations for the electron density, the electron current density and electron temperature, coupled the Poisson equation of the electrostatic potential. In some domain supplemented by the proper boundary conditions, we investigate the zero-electron-mass limit, the zero-relaxation-time limit and the Debye-length (quasi-neutral) limit, respectively. We show the strong convergence of the sequence of solutions and give the associated error estimates. 相似文献
98.
Four novel oxovanadium(IV) binuclear complexes have been synthesized, namely [(VO)2(IPHTA) (L)2SO4 (L denotes 2,2′-bipyridine (bpy); 1,10-phenanthroline (phen); 4,4′-dimethyl-2,2′-bipyridine (Me2bpy) and 5-nitro-1,10-phenanthroline (NO2-phen)), where IPHTA is the isophthalate dianon. Based on elemental analyses, molar conductivity measurements, IR and electronic spectra studies, it is proposed that these complexes have IPHTA-bridged structures and consist of two vanadium(IV) atoms in a square-pyramidal environment. The complexes [(VO)2(IPHTA)(Me2bpy)2]SO4 (1) and [(VO)2(IPHTA)(bpy)2]SO4 (2) were characterized by variable temperature magnetic susceptibility (4–300 K) and the data could be well fitted by the least-squares method to a susceptibility equation derived from the spin Hamiltonian operator,
. The exchange integral, J, was found to be −26.8 cm−1 for (1) and −31.0 cm−1 for (2). These results are commensurate with antifferomagnetic interactions between two oxovanadium(IV) ions within each molecule. The influence of different terminal ligands on magnetic interactions between the metals of this kind of complexes is also discussed. 相似文献
99.
IntroductionFreeradicalformationfromhalogenatedhydrocarbonshasreceivedconsiderableattentionbecauseofitsscientif icandenvironmentalrelevance .1 6 Thisreactionseemstoplayanimportantroleinvariousprocesses .Bond break ingreactionisapowerfulsynthetictooltoprov… 相似文献
100.
IntroductionThemethoxyradical (CH3O)isanimportantinter mediateinthephotochemicaloxidationofhydrocarbonsintheatmosphere ,1 3andplaysasignificantroleintrans formingnitricoxidetonitrogendioxide .4 Similarly ,thereactionmechanismsofhydroxylandcarbonmonoxide5,6ando… 相似文献